Genesis mechanism of geothermal water in Yinchuan Basin: Constraints from hydrochemistry and isotopes
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摘要:
地热资源具备可再生、能源利用效率高和节能减排等显著优势,是推动能源转型、实现 “双碳” 目标的重要可再生能源类型。银川盆地地热储量丰富,但因缺乏系统的水文地球化学与同位素研究,其地热水成因机制尚未明确,开发利用也缺乏科学规划与统一管理,不仅导致地热资源开发利用进程缓慢,还严重阻碍了当地经济的绿色快速发展。本研究以银川盆地典型地热井水样为研究对象,将其按区域划分为西部、中部和东部3组,同步采集研究区深层地下冷水样品作为对照,结合区域地质构造背景,通过系统分析测试地热水与地下冷水的水化学、同位素特征,深入探讨了研究区地热水的地球化学起源、径流循环过程、热源类型,并全面剖析了地热系统的成因机制。研究发现,该区域地热水化学类型主要为 Cl-Na 型和Cl·SO4-Na 型;氢氧同位素特征显示,地热水补给来源以大气降水为主,补给高程在
1616 ~2964 m;水化学特征结合氯、锶、硫同位素指示,地热水物质来源主要为高温条件下的水−岩相互作用、岩盐溶解及古沉积水输入。研究区地热水热储温度为 78.9~109.2 ℃,循环深度在3455.4 ~24794.0 m;离子比例系数和14C 测年结果表明,与西部、东部地热水相比,中部地热水的水化学组分含量最高,循环周期最长,循环深度也最深。通过地热水水化学特征分析及花岗岩生热率定量计算得出,研究区地热系统的热源主要为大地热流加热。本研究明确了银川盆地地热资源的关键水文地球化学特征与成因机制,建立了地热系统成因概念模型,为后续科学合理开发利用该地热资源、推动当地经济绿色高质量发展提供了重要的理论与实践依据。Abstract:ObjectiveGeothermal resources have advantages such as renewability, high energy utilization efficiency, and energy conservation and emission reduction. As an important renewable energy for promoting energy transition and achieving the "double carbon" goals, although the Yinchuan Basin is rich in geothermal reserves, the genesis of its geothermal water remains unclear due to the lack of systematic hydrogeochemical and isotopic research, and their development lacks scientific planning and unified management, which not only slows down the development process of geothermal resources but also seriously hinders the green rapid local economic development.
MethodsThis study focused on water samples from typical geothermal wells in the Yinchuan Basin and divided them into western, central, and eastern regions according to their locations. Combined with the regional geological structure background, by analyzing and testing the hydrochemical and isotopic characteristics of geothermal water and cold groundwater, the study investigated the geochemical origin, runoff circulation processes, and heat sources of geothermal water in the study area, and analyzed the genesis mechanism of the geothermal system.
ResultsThe results showed that the main hydrochemical types of geothermal water in this study area were Cl-Na type and Cl·SO4-Na type. Hydrogen and oxygen isotopes indicated that the geothermal water was mainly recharged by atmospheric precipitation, and the recharge elevation ranged from
1616 m to2964 m. Hydrochemical characteristics, combined with chlorine, strontium, and sulfur isotopes indicated that the material sources of geothermal water were mainly high-temperature conditions of water-rock interaction, rock salt dissolution, and the input of paleo-sedimentary water. Reservoir temperatures in the study area ranged from 78.9 °C to 109.2 °C, and the circulation depths of geothermal water ranged from3455.4 m to24794.0 m. The results of ion ratio coefficients and 14C dating showed that geothermal water in the central region had the highest hydrochemical component contents, the longest circulation period, and the greatest circulation depth compared with the western and eastern regions. Based on geothermal water hydrochemical characteristic analysis and quantitative calculation of granite heat production rates, it was calculated that the heat source of the geothermal system in the study area was mainly terrestrial heat flow, excluding magmatic heating and radioactive element decay heating.ConclusionThis study clarifies the key hydrogeochemical characteristics and genesis mechanism of geothermal resources in the Yinchuan Basin, and establishes a conceptual model of the geothermal system genesis, providing an important theoretical and practical basis for the subsequent scientific and rational development and utilization of geothermal resources and promoting green high-quality economic development in the region.
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表 1 研究区水样水化学组分
Table 1. Hydrochemical components of water samples from study area
样品编号 采样地点 采样深度/m 碱度/(mg·L−1) pH值 T/℃ TDS CO3 HCO3 Cl SO4 Ca K Mg Na Si B Li Sr Fe 电荷平衡/% ρB/(mg·L−1) ρB/(μg·L−1) SWQ 银川市兴庆区 / 168.40 7.50 55.20 5348.00 0.72 158.09 2568.06 2658.55 592.87 24.43 78.21 2591.77 21.35 20252.67 693.45 12575.65 918.67 7.60 TLCF 贺兰县 / 97.90 7.10 59.10 13630.00 0.23 82.72 11804.08 6209.23 1989.25 67.04 308.90 6454.76 26.29 9860.99 722.66 36021.21 989.11 −7.20 TLJN 永宁县 / 178.70 7.60 36.60 6106.00 1.00 175.36 3296.93 2631.03 830.40 16.91 375.75 2703.27 15.97 1824.54 170.44 14492.78 570.21 13.30 TMWQ 银川市西夏区 / 213.60 8.00 50.00 850.00 2.55 240.83 478.32 109.66 27.77 6.80 3.09 408.47 27.45 2261.68 76.81 377.15 148.94 −1.60 TSHSJ 银川市兴庆区 / 296.90 7.20 36.50 3848.00 0.65 322.52 2128.24 1789.36 585.62 88.33 101.07 1615.53 13.83 9057.06 1638.01 11641.13 1374.29 3.80 Y1* 银川市兴庆区 / − 7.00 67.50 16378.00 0.36 172.28 7941.00 2145.40 869.33 66.84 164.42 4860.00 26.46 101000.00 1140.00 46400.00 − −0.30 Y3* 银川市西夏区 / − 7.60 55.00 15543.00 1.19 157.19 8129.00 1718.00 946.90 45.20 263.90 4292.00 18.48 31040.00 1327.50 33000.00 − −2.20 CG01 银川市兴庆区 100 255.30 8.60 12.00 367.00 5.59 276.62 86.10 113.54 66.88 2.45 44.62 86.28 1.70 234.68 11.81 1254.74 160.46 4.60 CG02 银川市西夏区 100 109.80 9.60 15.00 152.00 14.32 89.10 37.94 21.27 10.90 3.44 14.13 43.83 <0 57.38 8.72 139.29 23.01 −1.00 CG03 中国外运门口 100 195.09 8.58 15.50 269.30 4.08 212.85 44.48 115.94 52.66 4.68 40.75 43.67 3.24 141.23 13.53 649.75 141.25 2.70 CG04 望远镇 100 199.06 8.85 15.40 469.30 7.77 213.02 222.93 56.09 19.88 5.61 22.18 195.86 <0 309.11 14.39 509.09 37.80 0.30 CG05 银川高速公路旁 100 281.73 9.61 13.50 628.00 44.87 207.44 174.93 441.23 22.09 1.53 21.24 291.49 3.26 949.59 7.83 392.88 58.75 −12.90 CG06 贺兰县 250 250.60 9.40 13.00 434.00 24.93 215.53 112.49 120.43 31.57 13.22 24.40 156.14 3.91 329.94 7.71 633.20 100.58 −0.20 CG07 贺兰县和平村村部门口 240 160.97 8.30 15.10 1215.00 2.08 174.78 621.17 320.92 87.19 4.58 111.15 329.58 <0 502.61 25.32 1162.94 193.34 1.10 CG08 永宁未仝村团支部对面 240 320.75 9.55 14.00 428.50 45.30 256.61 74.56 137.65 20.25 2.31 13.91 202.53 4.15 378.98 8.50 325.12 52.64 −1.70 CG09 永宁古光村 240 766.49 9.35 15.70 1948.00 82.08 550.65 692.92 581.03 7.70 10.98 174.32 878.28 <0 2086.33 99.77 53.76 123.00 7.10 CG10 金沙乡元亘金沙园西 240 200.38 9.41 15.50 279.00 21.90 174.76 47.84 72.08 17.21 9.08 14.67 104.38 1.92 316.63 8.63 312.44 37.35 −0.20 CG11 西夏区马场路 250 169.09 9.23 17.50 175.40 12.66 146.38 20.06 50.73 44.38 4.02 28.09 44.99 4.62 87.28 10.73 439.47 128.12 13.70 CG12 宁夏中房东方悦 150 364.40 9.10 13.50 744.10 24.65 360.32 237.62 430.85 24.09 3.94 34.36 350.92 <0 232.07 14.29 629.10 24.51 −9.10 CG13 兰星村村委会 250 183.19 9.29 14.90 1089.00 16.29 135.58 626.52 815.54 67.49 12.60 129.55 346.37 <0 557.88 26.27 1624.99 121.21 −14.80 CG14 贺兰县 250 173.30 10.00 15.00 907.00 42.56 68.37 549.20 451.48 31.78 5.73 27.97 414.92 <0 610.93 37.91 941.08 104.57 −12.90 ZK01 平罗县 250 214.95 10.10 13.60 1541.00 55.98 75.83 732.40 330.73 28.87 3.81 27.07 789.11 1.56 927.48 51.08 1005.61 128.35 9.00 ZK02 平罗县 250 61.67 9.96 11.70 2132.00 7.00 12.49 1123.09 485.45 227.45 18.00 190.38 783.09 1.04 841.07 49.69 5633.25 118.47 14.50 ZK03 平罗县 250 199.30 9.29 11.60 1262.00 16.81 159.50 546.51 300.68 58.81 8.03 80.24 513.08 0.78 723.07 38.11 1692.96 133.01 11.80 ZK04 平罗县 160 261.00 9.30 11.60 317.00 21.88 253.83 48.01 43.08 14.05 1.22 7.61 152.98 3.53 541.89 11.21 285.98 123.77 2.70 ZK05 平罗县 250 293.59 10.07 8.90 1126.00 75.10 132.97 420.59 222.27 22.00 2.49 24.06 516.24 1.46 878.69 32.65 641.43 52.13 6.30 ZK06 平罗县 250 171.20 9.60 18.50 1924.00 25.42 100.64 893.08 476.47 52.17 4.68 43.00 970.94 1.53 1114.41 75.62 1553.55 72.94 11.40 ZK07 惠农区 250 72.84 9.69 13.30 1166.00 9.47 34.32 548.02 336.65 95.09 4.59 69.60 439.07 1.13 547.36 82.59 2165.06 156.76 10.60 ZK08 惠农区 250 72.84 8.28 10.40 11100.00 1.07 65.47 6576.67 3267.09 472.38 20.52 511.15 5556.07 5.94 3976.13 397.32 8002.46 1960.34 9.60 ZK09 平罗县 240 126.63 9.00 8.10 2885.00 6.20 106.79 1526.61 853.82 198.24 6.62 160.14 1200.10 2.31 1254.11 74.59 4898.76 132.38 8.90 ZK10 平罗县 240 48.26 9.57 11.20 3268.00 3.85 15.70 1590.28 1304.10 353.54 5.37 101.48 1457.32 1.87 3524.32 131.85 9685.88 115.78 10.80 ZK11 惠农区 240 963.46 9.74 11.80 10270.00 183.58 371.65 5151.30 5444.20 14.78 12.56 210.16 6746.64 5.38 4634.71 133.69 352.47 176.41 5.90 ZK12 惠农区 240 61.67 8.98 12.20 10310.00 2.89 33.91 6058.80 3435.50 404.22 22.03 559.49 5298.26 4.95 3388.27 217.81 7120.08 170.12 10.20 ZK13 平罗县 250 362.86 9.92 8.80 884.90 82.52 215.83 304.01 122.48 16.56 1.70 12.56 398.15 2.53 983.07 20.84 418.64 60.41 1.90 ZK14 平罗县 240 237.74 9.25 12.80 638.10 20.04 229.02 229.42 97.31 18.34 1.07 4.40 305.66 3.82 696.88 10.59 307.48 225.99 4.50 ZK15 平罗县 220 193.05 9.39 13.50 188.20 18.73 173.20 16.30 5.56 26.05 1.01 6.32 60.04 1.97 129.89 3.99 366.48 93.84 −0.30 ZK16 平罗县 230 139.42 8.67 13.30 162.60 3.16 154.81 24.89 15.21 33.58 1.68 10.43 32.74 3.02 74.29 6.43 359.91 158.58 2.90 ZK17 平罗县 230 143.45 8.64 14.00 170.10 3.11 160.77 16.78 6.42 26.44 1.90 11.81 33.81 2.22 74.84 7.49 312.45 73.26 4.00 ZK18 大武口区 240 156.85 9.41 9.70 159.10 14.63 146.46 17.40 3.75 18.97 0.58 4.22 53.64 2.37 81.49 5.37 282.74 45.68 0.10 ZK19 大武口区 240 205.10 9.60 12.70 326.00 30.63 166.24 102.98 20.15 13.85 1.28 3.61 148.73 2.43 192.09 10.16 310.46 91.29 0.40 ZK20 惠农区 190 122.00 9.26 13.40 399.20 9.90 113.17 103.55 154.92 6.43 4.46 35.54 143.01 0.47 258.96 51.23 39.03 66.38 5.10 ZK21 惠农区 230 141.66 9.42 13.20 945.00 14.96 105.68 363.93 299.67 9.09 9.40 92.80 322.54 0.81 481.94 117.86 27.46 177.88 7.20 ZK22 贺兰县 230 126.91 9.14 10.70 155.60 7.10 129.30 16.83 1.97 20.33 1.39 9.58 36.58 1.58 69.19 6.11 279.52 66.27 6.60 ZK23 贺兰县 240 155.51 9.37 11.70 138.00 13.66 141.38 9.55 1.05 24.07 1.05 10.38 35.52 3.21 70.69 4.95 273.12 111.09 3.60 ZK24 西夏区 260 281.98 8.80 12.60 756.70 9.51 288.00 179.67 324.83 64.04 6.88 78.21 240.14 2.72 374.89 34.98 959.05 133.40 8.00 ZK25 金凤区 250 294.94 9.54 12.90 511.60 39.94 240.83 125.94 57.79 17.49 1.66 12.92 211.01 3.83 333.74 17.27 376.61 112.52 1.70 ZK26 利通区 260 60.60 9.70 11.10 6898.00 5.51 12.99 4047.12 2413.66 352.25 22.41 461.34 3345.89 2.97 2857.64 276.28 7886.15 136.47 10.50 ZK27 灵武市 240 283.76 10.13 12.20 358.30 79.39 129.12 88.46 18.27 13.68 2.51 12.17 157.32 1.33 554.29 12.62 335.22 136.02 0.30 ZK28 灵武市 250 42.90 9.61 14.90 2221.00 3.92 14.29 1134.34 688.00 206.05 7.61 194.72 774.67 1.16 1142.63 35.19 2743.60 140.79 13.00 ZK29 青铜峡市 210 105.91 8.96 15.50 804.40 5.02 97.60 334.33 241.72 84.91 5.61 64.02 242.43 0.88 302.88 22.04 1512.35 110.56 10.50 ZK30 兴庆区 210 128.70 9.40 13.50 1410.00 13.60 93.78 691.03 322.81 39.64 6.74 82.56 567.18 0.55 282.87 27.65 855.77 60.94 7.80 ZK31 贺兰县 280 42.90 9.50 12.10 3153.00 2.93 13.26 1947.54 1063.18 639.76 6.45 318.96 868.34 1.99 428.43 57.04 10518.47 196.65 11.60 ZK32 金凤区 130 242.20 9.34 10.60 408.60 20.58 211.13 71.17 91.77 29.39 2.78 41.87 120.77 1.30 381.88 17.13 601.34 66.88 8.50 ZK33 西夏区 230 154.15 8.86 13.00 345.00 5.39 158.18 84.50 73.19 43.65 4.02 41.54 69.04 3.22 153.45 16.38 425.65 193.20 10.50 ZK34 金凤区 270 73.29 9.53 13.40 138.10 8.72 61.93 10.31 16.21 14.05 6.72 4.51 21.16 0.72 92.49 12.53 151.88 42.08 2.20 ZK35 灵武市 230 67.48 9.75 12.00 4683.00 7.23 17.51 2745.64 1750.05 253.97 8.53 300.33 2020.51 2.94 2334.59 92.00 4916.06 368.91 4.70 ZK36 灵武市 200 69.27 9.44 13.30 5135.00 6.03 28.12 2754.88 1684.02 170.62 8.98 399.44 2505.68 3.21 2349.08 82.17 2851.23 159.01 14.60 ZK37 永宁县 60 177.85 9.35 15.10 392.30 16.30 144.55 137.69 61.50 36.20 2.45 39.96 116.20 0.97 329.12 12.99 848.21 85.10 8.30 ZK38 贺兰县 260 317.73 8.90 13.00 408.40 12.80 338.81 68.76 55.82 11.39 3.06 32.48 162.26 1.30 345.87 14.73 120.23 109.59 4.90 ZK39 永宁县 190 168.47 9.95 15.10 333.00 34.56 80.65 70.59 32.84 23.21 3.20 28.40 86.71 0.52 179.15 21.82 573.98 61.47 11.30 ZK40 金凤区 230 205.11 8.96 14.60 204.60 9.00 213.12 19.32 14.16 27.11 2.29 19.97 50.15 2.16 95.66 9.59 376.29 78.06 3.10 ZK41 永宁县 240 220.80 9.00 14.50 248.00 9.42 220.80 33.36 34.80 54.00 1.98 25.83 61.00 3.64 207.70 11.19 730.90 94.35 11.40 ZK42 永宁县 220 53.18 9.08 17.80 674.80 3.20 46.47 315.11 157.60 49.45 4.32 50.92 196.69 0.41 118.00 35.16 595.29 123.71 7.50 ZK43 青铜峡市 250 193.90 9.80 14.50 1424.00 32.43 95.18 544.34 545.17 8.07 10.50 121.29 637.35 1.73 535.03 113.83 57.91 87.00 12.00 ZK44 永宁县 240 319.07 9.76 15.00 281.90 61.13 219.12 20.56 25.50 14.34 2.09 10.25 137.41 5.61 341.34 13.03 236.39 63.26 −0.90 注:—表示未检出;均为单层水采样;*数据引自文献[15,18] 表 2 研究区水样同位素特征
Table 2. Isotopic characteristics of water samples in the study area
样品
编号δD/‰ δ18O/‰ δ34S-SO42−/
‰δ37Cl/
‰87Sr/86Sr/
‰14C/a BP 地热水 TMWQ −91.843 −12.1550 10.48 0.27 0.71421 6835 SWQ −82.424 − 9.0418 11.18 0.33 0.71122 8740 TLCF −82.204 − 9.3974 19.09 0.32 0.71173 26070 TLJN −82.915 −10.5760 13.94 0.32 0.71135 17310 Y1* −59.000 −6.500 — — — 22750 Y3* −79.000 −9.300 — — — 14360 TSHSJ −81.634 − 9.5967 11.98 0.24 0.71780 15230 地下
冷水样CG01 −77.923 −11.1630 — — — — CG02 −83.158 −11.9230 — — — — CG06 −91.928 −12.7860 — — — — CG14 −91.019 −12.8360 — — — — ZK04 −84.639 −12.0710 — — — — ZK06 −88.190 −12.3680 — — — — ZK19 −85.846 −11.2660 — — — — ZK26 −75.147 − 8.6823 — — — — ZK41 −86.974 −11.9160 — — — — ZK43 −85.027 −11.4930 — — — — 注:—表示未检出;*数据引自文献[26] 表 3 研究区地热水热储温度估算结果
Table 3. Estimated reservoir temperatures of geothermal water in the study area
地热
区域样品
编号石英温标(无
蒸汽散失)[49]/℃石英温标(蒸
汽散失)[49]/℃玉髓温
标[50]/℃Na-K温
标[51]/℃K-Mg温
标[51]/℃西部
地热区TMWQ 109.6 109.2 80.2 120.8 72.1 中部
地热区SWQ 97.7 99.0 67.5 95.0 64.3 TLCF 107.5 107.4 78.0 99.2 71.7 TLJN 84.9 87.9 53.9 78.4 40.3 Y1 107.8 107.7 78.3 111.7 79.2 Y3 91.2 93.4 60.6 99.8 64.5 东部
地热区TSHSJ 78.9 82.6 47.5 188.3 92.4 最小值 78.9 82.6 47.5 78.4 40.3 最大值 109.6 109.2 80.2 188.3 92.4 平均值 96.8 97.1 66.6 113.3 69.2 表 4 研究区地热水循环深度估算结果
Table 4. Estimated circulation depths of geothermal water in study area
地热区域 样品编号 采样温度/℃ 热储温度/℃ 循环深度/m 西部地热区 TMWQ 50.0 109.6 4408.4 中部地热区 SWQ 55.2 97.7 4303.8 TLCF 59.1 107.5 4779.1 TLJN 36.6 84.9 3679.7 Y1 67.5 107.8 4794.0 Y3 55.0 91.2 3987.7 东部地热区 TSHSJ 36.5 78.9 3455.4 表 5 研究区花岗岩样品铀、钍、钾含量及放射性生热率
Table 5. Uranium, thorium, and potassium contents and radioactive heat production rates of granite samples in the study area
样品
编号岩石
类型w(K)/% w(Th)/
(μg·g−1)w(U)/
(μg·g−1)生热率A/
(μW·m−3)R01 花岗岩 1.0322553 3.75 0.81 0.5645351 R02 花岗岩 4.5381064 0.59 0.21 0.5214304 R03 花岗岩 3.131617 0.17 0.14 0.3419827 -
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